Sun trine Mars in a natal chart means that the Sun, your core identity and the thing you run on, and Mars, the planet of drive, desire and the way you go after things, sit roughly 120 degrees apart in your chart, in signs of the same element. The trine is the aspect that flows. These two planets are not fighting each other or straining to connect. They speak the same language, and what you want tends to line up with who you are.
Spisce reads this trine when the Sun and Mars are within 6 degrees of exact. The closer the degree, the more clearly you feel it.
The trine usually joins signs four apart in the same element: fire to fire, earth to earth, air to air, water to water. That shared element is part of why the two planets cooperate so well. A fire Sun and a fire Mars, for instance, push in the same direction with the same kind of heat.